warning
Ugh, last time I had to set this card up with a Proxmox box, it just plain didn't work. I don't know if the adapter is failing or if I have a bad cable or just don't know how to computer, but it was a major headache. I recently bought a Panda PAU09 and it has been solid as it just plugs and plays in Linux via Proxmox without any jerking around with drivers and compiling stuff. So at this point I'd say go that route, but here's a few bits of info that hopefully are still relevant to the AWUS036ACH.
ALFA AWUS036ACH
Here's how to setup this card to get into monitor mode and start enumerating/attacking APs
Get into monitor mode
Run the "monitor" script from here to set your card in monitor mode
Scan all abg bands for specific wifi name
airodump-ng wlan0mon --essid "MEOW" --band abg